PUBLICATIONS

Tan, M.; Sandoval-Pauker, C.; Takacs, Z; Reinholdt, A. Metallaphosphinidene Coupling with a Phosphorus Ylide to Form a Phosphavinyl [P═CH2]− Ligand, 2026; 148, 25096–25106, DOI: 10.1021/jacs.6c06304

Chandran, A.,; Reinholdt, A. Flash Communication: A Glovebox-Friendly Synthesis of [CrCl3(THF)3] from CrCl2 and Trityl Chloride. Organometallics, 2026; 45, 1198–1202, DOI: 10.1021/acs.organomet.6c00088 

Chandran, A.,; Edin, S.; Tan, M.; Reinholdt, A. Stabilizing the E≡ N Triple Bonds in Pnictogen Mononitrides. Dalton Trans. 2026, DOI: 10.1039/D6DT00293E

Chandran, A.; Sandoval-Pauker, C.; Pinter, B.; Vosch, T.; Wilhelm, F.; Rogalev, A.; Pedersen, K. S.; Reinholdt, A. A Mixed-Valent and High-Spin Vanadium Phosphide. J. Am. Chem. Soc. 2026, 148, 9, 9629–9639. DOI: 10.1021/jacs.5c20647

Edin, S.; Sandoval-Pauker, C.; Yutronkie, N. J.; Takacs, Z.; Wilhelm, F.; Rogalev, A.; Pinter, B.; Pedersen, K. S.; Reinholdt, A. Unleashing Phosphorus Mononitride. Nat. Commun. 2025, 16, 5596. DOI: 10.1038/s41467-025-60669-6

Jafari, M. G.; Fehn, D.; Sandoval-Pauker, C.; Gau, M. R.; Meyer, K.; Pinter, B.; Mindiola, D. J.; Reinholdt, A. A Titanium Redox-Switch Enables Reversible C–C Bond Forming and Splitting Reactions. Chem. Sci. 2025, 16, 17714–17724. DOI: 10.1039/D5SC04824A

Xu, Y.; Reinholdt, A.; Antzutkin, O. N.; Forsyth, M.; Johansson, P.; Shah, F. U. Ionic Interaction Effects on the Structure and Dynamics of Orthoborate Ionic Materials. Cryst. Growth Des. 2024, 24, 8989–8998. DOI: 10.1021/acs.cgd.4c01030

Larsen, E. M. H.; Brock-Nannestad, T.; Skibsted, J.; Reinholdt, A.; Bendix, J. A Homoleptic AgIII Complex Stabilized by Succinimidate Ligands. Chem. Sci. 2024, 15, 18067–18075. DOI: 10.1039/D4SC04843A

Mohar, J. S.; Reinholdt, A.; Keller, T. M.; Carroll, P. J.; Telser, J.; Mindiola, D. J. A Mononuclear, Terminal Titanium(III) Imido. Chem. Commun. 2023, 59, 10101–10104. DOI: 10.1039/D3CC01758C

Jafari, M. G.; Fehn, D.; Reinholdt, A.; Hernández-Prieto, C.; Patel, P.; Gau, M. R.; Carroll, P. J.; Krzystek, J.; Liu, C.; Ozarowski, A.; Telser, J.; Delferro, M.; Meyer, K.; Mindiola, D. J. Tale of Three Molecular Nitrides: Mononuclear Vanadium(V) and (IV) Nitrides As Well As a Mixed-Valence Trivanadium Nitride Having a V3N4 Double-Diamond Core. J. Am. Chem. Soc. 2022, 144, 10201–10219. DOI: 10.1021/jacs.2c00276

Reinholdt, A.; Kwon, S.; Jafari, M. G.; Gau, M. R.; Carroll, P. J.; Lawrence, C.; Gu, J.; Baik, M.-H.; Mindiola, D. J. An Isolable Azide Adduct of Titanium(II) Follows Bifurcated Deazotation Pathways to an Imide. J. Am. Chem. Soc. 2022, 144, 527–537. DOI: 10.1021/jacs.1c11215

Reinholdt, A.; Bendix, J. Transition Metal Carbide Complexes. Chem. Rev. 2022, 122, 830–902. DOI: 10.1021/acs.chemrev.1c00404 Review

Reinholdt, A.; Jafari, M. G.; Sandoval-Pauker, C.; Ballestero-Martínez, E.; Gau, M. R.; Driess, M.; Pinter, B.; Mindiola, D. J. Phosphorus and Arsenic Atom Transfer to Isocyanides to Form π-Backbonding Cyanophosphide and Cyanoarsenide Titanium Complexes. Angew. Chem., Int. Ed. 2021, 60, 17595–17600. DOI: 10.1002/anie.202104688

Glent-Madsen, I.; Reinholdt, A.; Bendix, J.; Sauer, S. P. A. Importance of Relativistic Effects for Carbon as an NMR Reporter Nucleus in Carbide-Bridged [RuCPt] Complexes. Organometallics 2021, 40, 1443–1453. DOI: 10.1021/acs.organomet.1c00079

Reinholdt, A.; Staples, O.; Mindiola, D. J. Chromium(II) Complexes. In Comprehensive Coordination Chemistry III; Constable, E. C., Parkin, G., Que, L., Jr., Eds.; Elsevier: 2021; Vol. 4, pp 478–507. DOI: 10.1016/B978-0-08-102688-5.00012-X Book Chapter

Staples, O.; Reinholdt, A.; Mindiola, D. J. Chromium(III) Complexes. In Comprehensive Coordination Chemistry III; Constable, E. C., Parkin, G., Que, L., Jr., Eds.; Elsevier: 2021; Vol. 4, pp 508–551. DOI: 10.1016/B978-0-08-102688-5.00013-1 Book Chapter

Reinholdt, A.; Pividori, D.; Laughlin, A. L.; DiMucci, I. M.; MacMillan, S. N.; Jafari, M. G.; Gau, M. R.; Carroll, P. J.; Krzystek, J.; Ozarowski, A.; Telser, J.; Lancaster, K. M.; Meyer, K.; Mindiola, D. J. A Mononuclear and High-Spin Tetrahedral TiII Complex. Inorg. Chem. 2020, 59, 17834–17850. DOI: 10.1021/acs.inorgchem.0c02586

Mitcov, D.; Platunov, M.; Buch, C. D.; Reinholdt, A.; Døssing, A. R.; Wilhelm, F.; Rogalev, A.; Piligkos, S. Hard X-ray Magnetochiral Dichroism in a Paramagnetic Molecular 4f Complex. Chem. Sci. 2020, 11, 8306–8311. DOI: 10.1039/D0SC02709J

Reinholdt, A.; Alemayehu, A. B.; Gagnon, K. J.; Bendix, J.; Ghosh, A. Electrophilic Activation of Osmium-Nitrido Corroles: The Os≡N Triple Bond as a π-Acceptor Metallaligand in a Heterobimetallic OsVIN–PtII Complex. Inorg. Chem. 2020, 59, 5276–5280. DOI: 10.1021/acs.inorgchem.0c00654

Reinholdt, A.; Bendix, J. Platinum(II) as an Assembly Point for Carbide and Nitride Ligands. Chem. Commun. 2019, 55, 8270–8273. DOI: 10.1039/C9CC03411K

Reinholdt, A.; Majer, S. H.; Gelardi, R. M.; MacMillan, S. N.; Hill, A. F.; Wendt, O. F.; Lancaster, K. M.; Bendix, J. An Approach to Carbide-Centered Cluster Complexes. Inorg. Chem. 2019, 58, 4812–4819. DOI: 10.1021/acs.inorgchem.8b03222

Mitcov, D.; Pedersen, A. H.; Ceccato, M.; Gelardi, R. M.; Hassenkam, T.; Konstantatos, A.; Reinholdt, A.; Sørensen, M. A.; Thulstrup, P. W.; Vinum, M. G.; Wilhelm, F.; Rogalev, A.; Wernsdorfer, W.; Brechin, E. K.; Piligkos, S. Molecular Multifunctionality Preservation upon Surface Deposition for a Chiral Single-Molecule Magnet. Chem. Sci. 2019, 10, 3065–3073. DOI: 10.1039/C8SC04917C

Reinholdt, A.; Bendix, J.; Hill, A. F.; Manzano, R. A. Confluence of Disparate Carbido Chemistries: [WRuAu2(μ-C)2Cl3(CO)2(PCy3)2(Tp*)]. Dalton Trans. 2018, 47, 14893–14896. DOI: 10.1039/C8DT03851A

Pedersen, K. S.; Perlepe, P.; Aubrey, M. L.; Woodruff, D. N.; Reyes-Lillo, S. E.; Reinholdt, A.; Voigt, L.; Li, Z.; Borup, K.; Rouzières, M.; Samohvalov, D.; Wilhelm, F.; Rogalev, A.; Neaton, J. B.; Long, J. R.; Clérac, R. Formation of the Layered Conductive Magnet CrCl2(pyrazine)2 through Redox-Active Coordination Chemistry. Nat. Chem. 2018, 10, 1056–1061. DOI: 10.1038/s41557-018-0107-7

Reinholdt, A.; Hill, A. F.; Bendix, J. Synthons for Carbide Complex Chemistry. Chem. Commun. 2018, 54, 5708–5711. DOI: 10.1039/C8CC03596B

Reinholdt, A.; Bendix, J. Weakening of Carbide–Platinum Bonds as a Probe for Ligand Donor Strengths. Inorg. Chem. 2017, 56, 12492–12497. DOI: 10.1021/acs.inorgchem.7b01956

Morsing, T. J.; Reinholdt, A.; Sauer, S. P. A.; Bendix, J. Ligand Sphere Conversions in Terminal Carbide Complexes. Organometallics 2016, 35, 100–105. DOI: 10.1021/acs.organomet.5b00803

Reinholdt, A.; Vosch, T.; Bendix, J. Modification of σ-Donor Properties of Terminal Carbide Ligands Investigated Through Carbide–Iodine Adduct Formation. Angew. Chem., Int. Ed. 2016, 55, 12484–12487. DOI: 10.1002/anie.201606551

Reinholdt, A.; Herbst, K.; Bendix, J. Delivering Carbide Ligands to Sulfide-Rich Clusters. Chem. Commun. 2016, 52, 2015–2018. DOI: 10.1039/C5CC08918B

Temizsoy, M.; Sethi, W.; Reinholdt, A.; Schau-Magnussen, M.; Bendix, J.; Hammershøi, A. Stereoretentive Formylation of (S)-Proline: New Application of the Self-Regeneration of Stereo-Centres (SRS) Principle via Chelation to Cobalt(III). Dalton Trans. 2015, 44, 18438–18446. DOI: 10.1039/C5DT02674A

Reinholdt, A.; Vibenholt, J. E.; Morsing, T. J.; Schau-Magnussen, M.; Reeler, N. E. A.; Bendix, J. Carbide Complexes as π-Acceptor Ligands. Chem. Sci. 2015, 6, 5815–5823. DOI: 10.1039/C5SC02077H